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  • Essay / Synthesis methods of nanocrystalline silicate phosphors

    The trivalent europium ion (Eu3+) has attracted the attention of researchers for a long time for many reasons. It is the subject of special attention due to the strong luminescence in the red spectral region. Its even number of electrons in the outermost 4f shell has diverted researchers' attention toward it due to the theoretical importance of the structure. Rare earth-doped nanophosphors have been researched because, in display device or LED applications, they overcome the disadvantage of self-absorption and tunable luminescence. Yttrium orthosilicate (YSO) has proven to be an excellent host material for rare earth elements due to special properties such as water resistance, chemical resistance and visible light transparency. Furthermore, they exhibit superior properties due to thermal stability, wide energy band gap, low cost, non-toxicity, chemical resistance, high temperature resistance , low thermal expansion and high conductivity, multi-color phosphorescence, high resistance to acids, alkalis and oxygen. . Among silicate phosphors, YSOs doped with rare earth ions are widely studied in display applications. YSO has proven to be an excellent cathodoluminescent material and, doped with Eu3+, is a promising candidate for a time-domain coherent optical memory and red phosphor for lamps and display applications. Say no to plagiarism. Get a tailor-made essay on “Why violent video games should not be banned”?Get the original essayThe luminescence properties of Eu3+-doped compounds have been studied extensively in various forms of compounds, such as in solutions, compounds polymers, liquid crystals, glasses, etc. compounds have been prepared via various conventional methods. Silicate nanophosphors are synthesized by various routes such as solid-state, sol–gel, hydrothermal, co-precipitation, and spray pyrolysis reactions. It has also been established that the synthesis method and conditions influence the luminescence properties. In the present study, Eu3+-doped nanophosphorus YSO (1–9 mol%) was synthesized sonochemically. The prepared sample was calcined at 11,000°C and 13,000°C. Due to the quantum confinement effects of incorporating rare earth trivalent cations into a host lattice, the properties of the nanophosphorus are significantly enhanced. The Eu3+ doped YSO phosphor emits in the red region with appreciable color purity. The nanophosphorus is excited by near-ultraviolet light. A comprehensive study of YSO:Eu3+ synthesized via sonochemical method has not been reported so far. This study aims to probe the crystal structure of the prepared nanophosphorus by studying its photoluminescence. A reaction is a way in which energy interacts with matter. Controlling a reaction is nothing more than controlling matter and energy, or both. The preparation of nanoparticles requires effective control of the chemical reaction leading to their synthesis, which is a complex task. The method or process of synthesizing nanomaterials influences their properties. In order to prepare nanomaterials as needed, several reaction parameters such as time, energy input, and pressure are usually manipulated. But the main constraint lies in the choice of the appropriate energy source. Recently, sonochemical methods involving ultrasonic irradiation have gained importance because they provide rare reaction conditions superior to others.