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Essay / pH levels - 464
Introduction: In 1909, SPL Sorensen published an article in Biochem Z in which he discussed the effect of H1+ ions on enzyme activity. In this paper he coined the term pH to describe this effect and defined it as -log[H1+]. In 1924, Sorensen realized that the pH of a solution is a function of the “activity” of the H1+ ion and not the concentration and published a second article on the subject. A better definition would be pH=-log[aH1+ ], where aH1+ denotes the activity of the H1+ ion. The activity of an ion depends on many variables, including concentration. It is unfortunate that chemistry texts use a definition of pH that has been obsolete for over 50 years. Due to the difficulty of accurately measuring the activity of the H1+ ion for most solutions, the International Union of Pure and Applied Chemistry (IUPAC) and the National Bureau of Standards (NBS) have defined the pH as the reading on a pH meter that has been standardized against standard buffers. The following equation is used to calculate the pH of all solutions: The activity of the H1+ ion is determined as accurately as possible for the standard solutions used. The identity of these solutions varies from one authority to another, but all give the same pH values to ±0.005 pH units. The historical definition of pH is correct for solutions so dilute and so pure that H1+ ions are not influenced by anything except solvent molecules (usually water). In most solutions, the pH ...